Method for manufacturing seamless steel pipe for line pipe and seamless steel pipe for line pipe

ABSTRACT

There is provided a method for manufacturing a seamless steel pipe for line pipe, capable of improving the toughness of the seamless steel pipe for line pipe. A round billet having a chemical composition, by mass percent, of C: 0.02 to 0.15%, Si: at most 0.5%, and Mn: 0.5 to 2.5%, the balance being Fe and impurities, is heated. The heated round billet is piercing-rolled to produce a hollow shell. The hollow shell is elongated and rolled and sized to produce a seamless steel pipe. The seamless steel pipe is water cooled, and the water cooling is stopped when the temperature of the seamless steel pipe reaches at most 450° C. The water-cooled seamless steel pipe is quenched, and the quenched seamless steel pipe is tempered.

TECHNICAL FIELD

The present invention relates to a method for manufacturing a seamlesssteel pipe and a seamless steel pipe and, more particularly, to a methodfor manufacturing a seamless steel pipe for line pipe and a seamlesssteel pipe for line pipe.

BACKGROUND ART

A pipeline laid on the bottom of the sea allows a high-pressure fluid toflow therein. The pipeline is further subjected to repeated distortioncaused by waves and to a seawater pressure. Therefore, a steel pipe usedfor the pipeline on the bottom of the sea is required to have highstrength and high toughness.

If the wall thickness of a seamless steel pipe for line pipe isincreased, the high strength can be achieved. However, the increase inwall thickness is liable to cause brittle fracture and decreases thetoughness. Therefore, a seamless steel pipe for line pipe used on thebottom of the sea is especially required to have excellent toughness.

A method for manufacturing a seamless steel pipe for line pipe whileimproving the toughness has been disclosed in JP2000-104117A (PatentDocument 1). In the manufacturing method disclosed in Patent Document 1,the steel pipe temperature immediately after piercing-rolling is atleast 950° C., and the steel pipe is soaked at a temperature of 900 to1000° C. with the steel pipe temperature maintained above the Ar3 point.Then, the soaked steel pipe is cooled at a cooling rate of at least 5°C./sec.

Also, methods for manufacturing a steel pipe other than the seamlesssteel pipe for line pipe while improving the toughness have beendisclosed in JP63-215309A (Patent Document 2), JP9-3539A (PatentDocument 3), JP2008-266700A (Patent Document 4), JP3755163B (PatentDocument 5), and JP3855300B (Patent Document 6).

In the manufacturing method disclosed in Patent Document 2, a piercer, amandrel mill, a cooling apparatus, a reheating furnace, and a stretchreducer are used. A billet is pierced by the piercer to produce a hollowshell, and the hollow shell is elongated and rolled by the mandrel mill.Then, the elongated and rolled hollow shell is cooled to a temperatureof at most the Ar1 point by the cooling apparatus, and the cooledmaterial pipe is sized by the stretch reducer.

In the manufacturing method disclosed in Patent Document 3, afinish-rolled steel pipe is cooled from a temperature of at least theAr3 point at a cooling rate higher than that of air cooling. The cooledsteel pipe is tempered at a temperature of at most the Ac1 point.

In the manufacturing method disclosed in Patent Document 4, a sizedsteel pipe is acceleratedly cooled. The acceleratedly cooled steel pipeis held at a temperature of 350 to 600° C.

In the manufacturing method disclosed in Patent Document 5, afinish-rolled steel pipe is heated to a temperature of 850 to 1100° C.,and the heated steel pipe is quenched. The cooling rate for quenching isnot subject to any limitation.

In the manufacturing method disclosed in Patent Document 6, afinish-rolled steel pipe is cooled to a temperature of at most the Ar3point at a cooling rate of at least 80° C./sec, and the cooled steelpipe is quenched and tempered.

SUMMARY OF INVENTION Technical Problem

With the manufacturing method disclosed in Patent Document 1, thetoughness of the seamless steel pipe for line pipe is improved to somedegree. In recent years, however, the seamless steel pipe for line pipehas been required to have a further improved toughness. In themanufacturing methods disclosed in Patent Documents 2 to 6, themanufactured steel pipes are of steel types different from the seamlesssteel pipe for line pipe. Therefore, these manufacturing methods are notnecessarily suitable for improving the toughness of the seamless steelpipe for line pipe.

DISCLOSURE OF THE INVENTION

An objective of the present invention is to provide a method formanufacturing a seamless steel pipe for line pipe, capable of improvingthe toughness of the seamless steel pipe for line pipe.

The present inventors studied a method for further refining the crystalgrains of steel to improve the toughness of the seamless steel pipe forline pipe. As a result, the present inventors came up with an idea thatthe crystal grains of a steel pipe may be refined by acceleratedlycooling the steel pipe produced by hot working and then by quenching thesteel pipe. Specifically, a step of quenching is added between a step ofwater cooling (accelerated cooling) of the seamless steel pipe producedby a piercing machine and a continuous mill (a mandrel mill and a sizeror a stretch reducer) and a step of tempering. The crystal grains arerefined in the seamless steel pipe for line pipe manufactured by thismanufacturing method, so that the toughness is improved.

The present inventors further came up with an idea that if a watercooling stop temperature is decreased in the accelerated cooling, thecrystal grains may further be refined. The water cooling stoptemperature refers to the surface temperature of steel pipe at the timewhen water cooling is stopped in the accelerated cooling. If the watercooling stop temperature is low when the steel pipe for line pipe havinga surface temperature of at least the Ar3 point is water cooled, abainitic structure is produced in the steel. The bainitic structure isconsidered to be produced by lattice transformation like martensiticstructure, and includes a highly dense lattice defect such asdislocation. If the steel pipe having a bainitic structure is heated tothe quenching temperature, fine γ grains are produced with the highlydense lattice defect being an initiation site. Therefore, the crystalgrains of the quenched and tempered steel pipe are refined, so that thetoughness of steel pipe is improved.

Based on the above-described theory, the present inventors examined therelationship between the water cooling stop temperature in acceleratedcooling and the toughness. The relationship between water cooling stoptemperature and toughness is shown in FIG. 1. FIG. 1 was obtained by themethod described below. A plurality of billets each having the chemicalcomposition given in Table 1 were prepared.

TABLE 1 Chemical composition (mass %, balance being Fe and impuritiesother than P, S and Al) C Si Mn P S Cu Cr Ni Mo Ti V Nb Al 0.06 0.3 1.30.01 0.001 — 0.2 — 0.1 0.03 — 0.03 0.05

The billets were heated by a heating furnace. Successively, the billetswere piercing-rolled into hollow shells by a piercing machine. Then, thehollow shells were elongated and rolled by an elongation rolling mill,and the hollow shells were sized by a sizing mill, whereby a pluralityof seamless steel pipes for line pipe were produced. Successively, theproduced seamless steel pipes were water cooled (acceleratedly cooled).At this time, the water cooling stop temperature was changed for everyseamless steel pipe. The surface temperatures of all of the seamlesssteel pipes at the time when water cooling was started were 1100° C.After cooling, the seamless steel pipes were quenched at a quenchingtemperature of 950° C., and soaked for 40 minutes. After quenching, theseamless steel pipes were tempered at a tempering temperature of 650°C., and soaked for 30 minutes. By the above-described process, seamlesssteel pipes for line pipe were manufactured.

From a central portion of the wall thickness of each of the manufacturedseamless steel pipes for line pipe, V-notch specimen conforming to JIS Z2202 was sampled. By using this V-notch specimen, the Charpy impact testconforming to JIS Z 2242 was conducted to determine an energy transitiontemperature vTE. Thereby, a curve C1 shown in FIG. 1 was obtained.

Referring to FIG. 1, as the water cooling stop temperature decreased,the energy transition temperature vTE (° C.) decreased. Further, theslope of the curve C1 changed at the water cooling stop temperature of450° C. More specifically, when the water cooling stop temperaturedecreased, the energy transition temperature decreased rapidly until thewater cooling stop temperature reached 450° C., and on the other hand,in the temperature range defined below 450° C., even if the watercooling stop temperature decreased, the energy transition temperaturedid not decrease so much. That is, the curve C1 had an inflection pointat the water cooling stop temperature of 450° C.

Based on the above-described findings, the present inventors completedthe inventions described below.

The method for manufacturing a seamless steel pipe for line pipe inaccordance with the present invention includes the steps of heating around billet having a chemical composition including, by mass percent,C: 0.02 to 0.15%, Si: at most 0.5%, and Mn: 0.5 to 2.5%, the balancebeing Fe and impurities, producing a hollow shell by piercing-rollingthe heated round billet, producing a seamless steel pipe by elongationrolling and sizing the hollow shell, water cooling the produced seamlesssteel pipe and stopping water cooling when the temperature of theseamless steel pipe reaches at most 450° C., quenching the water-cooledseamless steel pipe, and tempering the quenched seamless steel pipe.

Preferably, the method for manufacturing a seamless steel pipe for linepipe further includes a step of heating the produced seamless steel pipeto 900 to 1100° C. In the water cooling step, the heated seamless steelpipe is water cooled.

Preferably, the chemical composition of the round billet furtherincludes one or more types selected from a group of Cu: at most 1.5%,Ni: at most 1.5%, Cr: at most 1.0%, Mo: at most 0.8%, V: at most 0.2%,Nb: at most 0.06%, and Ti: at most 0.05%.

The seamless steel pipe for line pipe in accordance with the presentinvention is manufactured by the above-described manufacturing method.

BRIEF DESCRIPTION OF DRAWINGS

FIG. 1 is a diagram showing the relationship between energy transitiontemperature and water cooling stop temperature of a seamless steel pipefor line pipe in accordance with the present invention.

FIG. 2 is a block diagram showing a configuration of a manufacturingequipment line for a seamless steel pipe for line pipe in accordancewith the present invention.

FIG. 3 is a flowchart showing a manufacture flow of a seamless steelpipe for line pipe using the manufacturing equipment line shown in FIG.2.

FIG. 4 is a diagram showing a change in surface temperature of amaterial being processed in steps in the manufacture flow shown in FIG.3.

FIG. 5 is a diagram showing the relationship between strength and watercooling stop temperature of a seamless steel pipe for line pipe ofexample 1.

FIG. 6 is a diagram showing the relationship between strength and watercooling stop temperature of a seamless steel pipe for line pipe ofexample 2.

FIG. 7 is a diagram showing the relationship between energy transitiontemperature and water cooling stop temperature of a seamless steel pipefor line pipe of example 2.

BEST MODE FOR CARRYING OUT THE INVENTION

An embodiment of the present invention will now be described in detailwith reference to the drawings. In the drawings, the same symbols areapplied to the same or equivalent portions, and the explanation thereofis not repeated.

Chemical Composition

A seamless steel pipe for line pipe in accordance with the embodiment ofthe present invention has a chemical composition described below.Hereunder, an ideogram of % relating to an alloying element refers to amass percent.

C: 0.02 to 0.15%

Carbon (C) increases the strength of steel. To provide a strengthnecessary for a line pipe, the lower limit value of C content is 0.02%.On the other hand, if carbon is contained excessively, the toughness ofthe weld heat affected zone of the welded portion and the base metal ofthe line pipe decreases. Therefore, the upper limit value of C contentis 0.15%. The C content is preferably 0.04 to 0.12%, further preferably0.04 to 0.09%.

Si: at most 0.5%

Silicon (Si) deoxidizes steel. However, if silicon is containedexcessively, the toughness of steel decreases. Therefore, the Si contentis at most 0.5%. The Si content is preferably 0.05 to 0.35%.

Mn: 0.5 to 2.5%

Manganese (Mn) enhances the hardenability of steel, and increases thestrength of steel. To provide a strength necessary for a line pipe, thelower limit value of Mn content is 0.5%. On the other hand, if manganeseis contained excessively, manganese segregates, which results in adecrease in the toughness of the weld heat affected zone and the basemetal. Therefore, the upper limit value of Mn content is 2.5%. The Mncontent is preferably 0.5 to 2.2%.

The balance is iron (Fe) and impurities. The impurities includephosphorus (P), sulfur (S), oxygen (O), nitrogen (N), and aluminum (Al).Phosphorus causes center segregation. Sulfur forms MnS with Mn, anddecreases the toughness of steel. Oxygen reduces the cleanliness ofsteel. Nitrogen forms a solid solution in the steel, which results in adecrease in the toughness of steel. Aluminum deoxidizes steel; however,aluminum reduces the cleanliness of steel, and decreases the toughnessthereof. Therefore, in the present invention, aluminum is an impurity.

The P content is preferably at most 0.015%. The S content is preferablyat most 0.004%. The 0 content is preferably at most 0.01%. The N contentis preferably at most 0.007%. The Al content is preferably at most0.05%.

As the chemical composition of the seamless steel pipe for line pipe inaccordance with this embodiment, the optional element(s) described belowmay be contained further.

All of copper (Cu), nickel (Ni), chromium (Cr), and molybdenum (Mo)enhance the hardenability of steel, and increase the strength of steel.Hereunder, these elements are described in detail.

Cu: at most 1.5%

Copper (Cu) is an optional element. Copper enhances the hardenability ofsteel, and increases the strength of steel. If even a slight amount ofcopper is contained, the above-described effects can be achieved. The Cucontent is preferably at least 0.05%. On the other hand, if copper iscontained excessively, the weldability of steel decreases. Further,copper reduces the grain boundary strength at high temperatures, whichmakes the steel liable to be cracked at the time of hot rolling.Therefore, the Cu content is at most 1.5%.

Ni: at most 1.5%

Nickel (Ni) is an optional element. Nickel enhances the hardenability ofsteel, and increases the strength of steel. If even a slight amount ofnickel is contained, the above-described effects can be achieved. The Nicontent is preferably at least 0.05%. On the other hand, if nickel iscontained excessively, the above-described effects saturate. Therefore,the Ni content is at most 1.5%.

Cr: at most 1.0%

Chromium (Cr) is an optional element. Chromium enhances thehardenability of steel, and increases the strength of steel. Further,chromium enhances the temper softening resistance of steel. If even aslight amount of chromium is contained, the above-described effects canbe achieved. The Cr content is preferably at least 0.02%. On the otherhand, if chromium is contained excessively, the weldability of steeldecreases, and also the toughness of steel decreases. Therefore, the Crcontent is at most 1.0%.

Mo: at most 0.8%

Molybdenum (Mo) is an optional element. Molybdenum enhances thehardenability of steel, and increases the strength of steel. If even aslight amount of molybdenum is contained, the above-described effectscan be achieved. The Mo content is preferably at least 0.02%. On theother hand, if molybdenum is contained excessively, the toughness ofsteel decreases, and also the weldability of steel decreases. Therefore,the Mo content is at most 0.8%.

All of vanadium (V), niobium (Nb), and titanium (Ti) precipitatecarbo-nitrides to increase the strength and toughness of steel.Hereunder, these elements are described in detail.

V: at most 0.2%Nb: at most 0.06%

Both of vanadium (V) and niobium (Nb) are optional elements. Both ofvanadium and niobium produce carbo-nitrides, and contribute to refiningof crystal grains of steel. Therefore, vanadium and niobium increase thestrength and toughness of steel. If even a slight amount of vanadiumand/or niobium are contained, the above-described effects can beachieved. The V content is preferably at least 0.01%, and the Nb contentis preferably at least 0.01%. On the other hand, if vanadium and niobiumare contained excessively, the toughness of the welded portion of steeldecreases. Therefore, the V content is at most 0.2%, and the Nb contentis at most 0.06%. The Upper limit value of V content is preferably 0.1%,and the upper limit value of Nb content is 0.03%.

Ti: at most 0.05%

Titanium (Ti) is an optional element. Titanium produces carbo-nitrides,and contributes to refining of crystal grains of steel. Therefore,titanium increases the strength and toughness of steel. If even a slightamount of titanium is contained, the above-described effects can beachieved. The Ti content is preferably at least 0.002%. However, iftitanium is contained excessively, the toughness of steel ratherdecreases. Therefore, the Ti content is at most 0.05%. The Upper limitvalue of Ti content is preferably 0.03%

Manufacturing Equipment

FIG. 2 is a block diagram showing one example of a manufacturing linefor the seamless steel pipe for line pipe in accordance with thisembodiment. Referring to FIG. 2, the manufacturing line includes aheating furnace 1, a piercing machine 2, an elongation rolling mill 3, asizing mill 4, a holding furnace 5, a water cooling apparatus 6, aquenching apparatus 7, and a tempering apparatus 8. Between theapparatuses, a plurality of transfer rollers are arranged. In FIG. 2,the quenching apparatus 7 and the tempering apparatus 8 are included inthe manufacturing line. However, the quenching apparatus 7 and thetempering apparatus 8 may be arranged separately from the manufacturingline. In other words, the quenching apparatus 7 and the temperingapparatus 8 may be arranged off-line.

Manufacturing Method

FIG. 3 is a flowchart showing a manufacturing process of the seamlesssteel pipe in accordance with this embodiment. FIG. 4 is a diagramshowing a change in surface temperature of a material being rolled (around billet, a hollow shell, and a seamless steel pipe) with respect totime during the manufacture.

Referring to FIGS. 3 and 4, in the method for manufacturing the seamlesssteel pipe for line pipe in accordance with this embodiment, first, around billet is heated by the heating furnace 1 (S1). Successively, theheated round billet is hot worked into a seamless steel pipe (S2 andS3). Specifically, the round billet is piercing-rolled into a hollowshell by the piercing machine 2 (S2), and further, the hollow shell isrolled into the seamless steel pipe by the elongation rolling mill 3 andthe sizing mill 4 (S3). The seamless steel pipe produced by hot workingis heated to a predetermined temperature as necessary by the holdingfurnace 5 (S4). Successively, the seamless steel pipe is water cooled(acceleratedly cooled) by the water cooling apparatus 6 so that thesurface temperature of the seamless steel pipe is at most 450° C. (S5).The water cooled seamless steel pipe is quenched by the quenchingapparatus 7 (S6), and is tempered by the tempering apparatus 8 (S7).Hereunder, each of the steps is explained in detail.

Heating Step (S1)

First, a round billet is heated by the heating furnace 1. The heatingtemperature is preferably 1050 to 1300° C. If the round billet is heatedat a temperature in this temperature range, the hot workability of theround billet at the piercing-rolling time is high, and the production ofsurface defects is restrained. Also, if the round billet is heated at atemperature in this temperature range, the coarsening of crystal grainsis restrained. The heating furnace 1 is a well-known walking beamfurnace or rotary furnace, for example.

Piercing-Rolling Step (S2)

The round billet is taken out of the heating furnace 1, and the heatedround billet is piercing-rolled by the piercing machine 2. The piercingmachine 2 has a well-known configuration. Specifically, the piercingmachine 2 includes a pair of conical rolls and a plug arranged betweenthe conical rolls. The piercing machine 2 is preferably a toe angle-typepiercing machine. This is because piercing-rolling can be performed at ahigh pipe expansion rate.

Elongation Rolling Step and Sizing Step (S3)

Next, the hollow shell produced by the piercing mill is elongated androlled by the elongation rolling mill 3. The elongation rolling mill 3includes a plurality of roll stands arranged in series. The elongationrolling mill 3 is a mandrel mill, for example. Successively, theelongated and rolled hollow shell is sized by the sizing mill 4 toproduce a seamless steel pipe. The sizing mill 4 includes a plurality ofroll stands arranged in series. The sizing mill 4 is a sizer or astretch reducer, for example.

The outer surface temperature of the hollow shell rolled by the rearmostroll stand of the plurality of roll stands of the sizing mill 4 isdefined as a “finishing temperature”. The finishing temperature ismeasured, for example, by a temperature sensor disposed on the deliveryside of the rearmost roll stand of the sizing mill 4. The finishingtemperature is preferably at least the A3 point (more specifically, theAc3 point) as shown in FIG. 4, further preferably at least 900° C., andstill further preferably at least 950° C. The Ac3 point of the seamlesssteel pipe having the chemical composition of the present invention is750 to 950° C. At a finishing temperature of 900° C. or higher, in thehollow shell being subjected to sizing, the heat loss caused by rollheat dissipation is small. Therefore, the temperature unevenness of theproduced seamless steel pipe can be reduced.

A heating furnace may be disposed between the elongation rolling mill 3and the sizing mill 4. In this case, the elongated and rolled hollowshell is heated by the heating furnace, and the heated material pipe issized by the sizing mill 4. Therefore, the material pipe temperature atthe time of sizing increases, so that the load applied to the sizingmill 4 is reduced.

Reheating Step (S4)

A reheating step (S4) is carried out as necessary. In other words, thereheating step need not necessarily be carried out. In the case wherethe reheating step is not carried out, in FIG. 3, the process proceedsfrom step S3 to step S5. Also, in the case where the reheating step isnot carried out, in FIG. 2, the holding furnace 5 is not provided.

In the case where the reheating step is carried out, the producedseamless steel pipe is charged into the holding furnace 5 and is heated.Thereby, the temperature unevenness of the produced seamless steel pipecan be reduced. The heating temperature in the holding furnace 5 is theAr3 point to 1100° C., preferably 900 to 1100° C., and furtherpreferably 950 to 1100° C. If the heating temperature is lower than theAr3 point, the a phase precipitates and the micro-structure becomesnonuniform, so that the variations in strength increase. On the otherhand, if the heating temperature exceeds 1100° C., the crystal grainscoarsen. The heating time is preferably 1 to 30 minutes.

Water Cooling Step (S5)

The seamless steel pipe produced in step S3 or the seamless steel pipereheated in step S4 is water cooled (acceleratedly cooled) by the watercooling apparatus 6. The surface temperature of the seamless steel pipejust before water cooling is substantially the same as the finishingtemperature or the heating temperature in the holding furnace. That is,the surface temperature of the seamless steel pipe just before watercooling is at least the Ar3 point, preferably at least 900° C., andfurther preferably at least 950° C.

The water cooling apparatus 6 includes a plurality of rotating rollers,a laminar stream device, and a jet stream device. The plurality ofrotating rollers are arranged in two rows, and the seamless steel pipeis arranged between the plurality of rotating rollers arranged in tworows. At this time, each of the two-row rotating rollers comes intocontact with a lower portion on the outer surface of the seamless steelpipe. When the rotating rollers rotate, the seamless steel pipe rotatesaround the axis thereof. The laminar stream device is arranged above therotating rollers, and sprinkles water onto the seamless steel pipe fromabove. At this time, the water sprinkled onto the seamless steel pipeforms a laminar stream. The jet stream device is disposed near the endof the seamless steel pipe placed on the rotating rollers, and injects ajet stream from the end of the seamless steel pipe into the steel pipe.By the laminar stream device and the jet stream device, the outer andinner surfaces of seamless steel pipe are cooled at the same time.

The water cooling apparatus 6 cools the seamless steel pipe until thesurface temperature of seamless steel pipe reaches a temperature of atmost 450° C. In other words, the water cooling stop temperature is atmost 450° C. With the water cooling stop temperature at most 450° C.,the micro-structure is subjected to bainitic transformation as describedabove. By performing quenching in the subsequent step, the crystalgrains of the seamless steel pipe are refined further. As the result,the toughness of the seamless steel pipe for line pipe is improved.

The water cooling stop temperature is preferably at least 300° C.,further preferably at least 350° C., and still further preferably atleast 400° C. The higher the water cooling stop temperature is in therange defined below 450° C., the shorter the required time is forheating the seamless steel pipe to the quenching temperature at the timeof quenching in the subsequent step. Also, the quantity of heat requiredfor heating the seamless steel pipe to the quenching temperature can bereduced.

The cooling rate of the water cooling apparatus 6 is preferably at least10° C./sec. The water cooling apparatus 6 may be an apparatus other thanthe above-described apparatus including the rotating rollers, thelaminar stream device, and the jet stream device. For example, the watercooling apparatus 6 may be a water tank. In this case, the seamlesssteel pipe produced in step S3 is immersed in the water tank, and iscooled. Such a cooling method is called “dip cooling”. Also, the watercooling apparatus 6 may consist of the laminar stream device only. Insum, the type of the water cooling apparatus 6 is not subject to anyrestriction as far as the seamless steel pipe can be cooled at a coolingrate of at least 10° C./sec.

It is preferable that the water cooling apparatus 6 and the quenchingapparatus 7 for the next step be arranged continuously. The reason forthis is that as the quenching apparatus 7 is closer to the water coolingapparatus 6, the quantity of heat required for heating the water-cooledseamless steel pipe to the quenching temperature can be reduced.

Quenching Step (S6)

The seamless steel pipe having been water cooled by the water coolingapparatus 6 is quenched. More specifically, the seamless steel pipe isheated and soaked at a quenching temperature. After heating and soaking,the seamless steel is cooled rapidly by water. The quenching temperatureis preferably higher than the Ac3 point and at most 1000° C. When theseamless steel pipe is heated to the above-described quenchingtemperature, the micro-structure of seamless steel pipe transforms frombainite to a fine austenitic structure. That is, reverse transformationtakes place. At this time, the crystal grains are refined. That is, byperforming accelerated cooling in step S5 and making the water coolingstop temperature at most 450° C., the refining of crystal grains can bepromoted in the quenching step.

If the quenching temperature is lower than the Ac3 transformation point,the reverse transformation does not take place sufficiently. On theother hand, if the quenching temperature exceeds 1000° C., the crystalgrains coarsen. The soaking time in quenching is preferably 10 secondsto 30 minutes.

Tempering Step (S7)

The quenched steel pipe is tempered. The tempering temperature is atmost Ac1 point, and is regulated based on desired dynamic properties.The Ac1 point of the seamless steel pipe having the chemical compositionof the present invention is 680 to 720° C. By tempering, the strengthgrade of the seamless steel pipe of the present invention can beregulated to at least X60 based on the API standard (the yield stress:at least 415 MPa, the tensile strength: at least 520 MPa). Thevariations in tempering temperature are preferably ±10° C., furtherpreferably ±5° C. If the variations in tempering temperature are small,the desired dynamic properties are achieved easily.

In the above-described manufacturing method, accelerated cooling inwhich the water cooling stop temperature is defined to be at most 450°C. is performed (S5), and thereafter quenching is performed (S6). Bythese steps, the refining of crystal grains is promoted. Therefore, themanufactured seamless steel pipe for line pipe has an excellenttoughness as described above.

Example 1

Seamless steel pipes for line pipe each having the chemical compositiongiven in Table 1 were manufactured, and the strength and toughnessthereof were examined.

Examination Method

A plurality of billets each having the chemical composition given inTable 1 were produced. The produced billets were heated by the heatingfurnace, and then, the billets were piercing-rolled by the piercingmachine to produce hollow shells. Successively, the hollow shells wereelongated and rolled by the mandrel mill, and then, were sized by thesizer, whereby a plurality of seamless steel pipes for line pipe wereproduced. Successively, the produced steel pipes were water cooled(acceleratedly cooled). At this time, the water cooling stop temperaturewas changed for every steel pipe. The finishing temperatures of all theseamless steel pipes were 1100° C. The cooled seamless steel pipes werequenched at a quenching temperature of 950° C., and were soaked for 40minutes. After quenching, the seamless steel pipes were tempered at atempering temperature of 650° C., and were soaked for 30 minutes. By theabove-described steps, seamless steel pipes for line pipe weremanufactured.

Examination of Strength

From a central portion of the wall thickness of each of the manufacturedseamless steel pipes, a tensile test specimen conforming to JIS Z 2201was sampled. By using this tensile test specimen, a tensile testconforming to JIS Z 2241 was conducted in the atmosphere of normaltemperature (25° C.). By the tensile test, the yield stress and tensilestrength were determined. In this example, the yield stress wasdetermined by the 0.5% total elongation method.

Examination of Toughness

From a central portion of the wall thickness of each of the manufacturedseamless steel pipes for line pipe, a V-notch specimen conforming to JISZ 2202 was sampled. By using this V-notch specimen, the Charpy impacttest conforming to JIS Z 2242 was conducted to determine an energytransition temperature vTE

Examination Results

The relationship between the obtained yield stress and tensile strengthand the water cooling stop temperature is shown in FIG. 5. In FIG. 5,symbol S1 denotes yield stress, and symbol S2 denotes tensile strength.Also, the relationship between the obtained energy transitiontemperature and the water cooling stop temperature is shown in FIG. 1.Referring to FIG. 1, the slope of the curve C1 changed at the watercooling stop temperature of 450° C. More specifically, when the watercooling stop temperature decreased, the energy transition temperaturedecreased rapidly until the water cooling stop temperature reached 450°C., and on the other hand, in the temperature range defined below 450°C., even if the water cooling stop temperature decreased, the energytransition temperature did not decrease so much. In the case where thewater cooling stop temperature was at most 450° C., the energytransition temperature was at most −55° C., showing a satisfactorytoughness.

On the other hand, referring to FIG. 5, in the case where the watercooling stop temperature was at most 450° C., the yield stress was atleast 450 MPa, and the tensile strength was at least 540 MPa. Therefore,the strength grade of the sample in the case where the water coolingstop temperature was at most 450° C. was at least X60 of the APIstandard (the yield stress: at least 415 MPa, the tensile strength: atleast 520 MPa).

Example 2

A plurality of billets each having the chemical composition given inTable 2 were manufactured.

TABLE 2 Chemical composition (mass %, balance being Fe and impuritiesother than P, S and Al) C Si Mn P S Cu Cr Ni Mo Ti V Nb Al 0.06 0.1 1.50.01 0.001 0.2 0.3 0.3 0.3 0.003 0.05 — 0.04

Examination Method

By the same manufacturing method as that in example 1, steel pipes forline pipe were manufactured by using the billets, and by the sametesting method as that in example 1, the relationship between thestrength (yield stress and tensile strength) and the water cooling stoptemperature and the relationship between the energy transitiontemperature vTE (° C.) and the water cooling stop temperature weredetermined. In example 2, the finishing temperature of seamless steelpipe was 1050° C. In quenching, the quenching temperature was 920° C.,and the soaking time was 20 minutes. In tempering, the temperingtemperature was 650° C., and the soaking time was 30 minutes. Otherconditions were the same as those in example 1.

Examination Results

The relationship between the obtained yield stress and tensile strengthand the water cooling stop temperature is shown in FIG. 6. In FIG. 6,symbol S1 denotes yield stress, and symbol S2 denotes tensile strength.Also, the relationship between the obtained energy transitiontemperature and the water cooling stop temperature is shown in FIG. 7.

Referring to FIG. 7, as shown in FIG. 1, until the water cooling stoptemperature reached 450° C., the energy transition temperature decreasedrapidly with the decrease in cooling water stop temperature, and in thetemperature range defined below 450° C., even if the water cooling stoptemperature decreased, the energy transition temperature did notdecrease so much. In the case where the water cooling stop temperaturewas at most 450° C., the energy transition temperature was at most −60°C., showing a satisfactory toughness.

Referring to FIG. 6, in the case where the water cooling stoptemperature was at most 450° C., the yield stress was at least 530 MPa,and the tensile strength was at least 620 MPa. Therefore, the strengthgrade of the sample in the case where the water cooling stop temperaturewas at most 450° C. was at least X70 of the API standard (the yieldstress: at least 485 MPa, the tensile strength: at least 570 MPa).

The above is a description of embodiments of the present invention, andthe above-described embodiments are merely examples for carrying out thepresent invention. Therefore, the present invention is not limited tothe above-described embodiments, and the above-described embodiments canbe modified as appropriate without departing from the spirit of theinvention.

1. A method for manufacturing a seamless steel pipe for line pipe,comprising the steps of: heating a round billet having a chemicalcomposition comprising, by mass percent, C: 0.02 to 0.15%, Si: at most0.5%, and Mn: 0.5 to 2.5%, the balance being Fe and impurities;producing a hollow shell by piercing-rolling the heated round billet;producing a seamless steel pipe by elongation rolling and sizing thehollow shell; water cooling the seamless steel pipe and stopping watercooling when the temperature of the seamless steel pipe reaches at most450° C.; quenching the water-cooled seamless steel pipe; and temperingthe quenched seamless steel pipe.
 2. The method for manufacturing aseamless steel pipe for line pipe according to claim 1, wherein themethod further comprises a step of heating the produced seamless steelpipe to 900 to 1100° C.; and in the water cooling step, the heatedseamless steel pipe is water cooled.
 3. The method for manufacturing aseamless steel pipe for line pipe according to claim 1, wherein thechemical composition further comprises one or more types selected from agroup of Cu: at most 1.5%, Ni: at most 1.5%, Cr: at most 1.0%, Mo: atmost 0.8%, V: at most 0.2%, Nb: at most 0.06%, and Ti: at most 0.05%. 4.The method for manufacturing a seamless steel pipe for line pipeaccording to claim 2, wherein the chemical composition further comprisesone or more types selected from a group of Cu: at most 1.5%, at most1.5%, Cr: at most 1.0%, Mo: at most 0.8%, V: at most 0.2%, Nb: at most0.06%, and Ti: at most 0.05%.
 5. A seamless steel pipe for line pipehaving a chemical composition comprising, by mass percent, C: 0.02 to0.15%, Si: at most 0.5%, and Mn: 0.5 to 2.5%, the balance being Fe andimpurities, and manufactured by hot working followed by water cooling,the water cooling being stopped when the temperature of the seamlesssteel pipe reaches at most 450° C., and further by quenching andtempering.
 6. The seamless steel pipe for line pipe according to claim5, wherein the seamless steel pipe is heated to 900 to 1100° C. afterbeing hot worked and before being water cooled.
 7. The seamless steelpipe for line pipe according to claim 5, wherein the chemicalcomposition further comprises one or more types selected from a group ofCu: at most 1.5%, Ni: at most 1.5%, Cr: at most 1.0%, Mo: at most 0.8%,V: at most 0.2%, Nb: at most 0.06%, and Ti: at most 0.05%.
 8. Theseamless steel pipe for line pipe according to claim 6, wherein thechemical composition further contains one or more types selected from agroup of Cu: at most 1.5%, at most 1.5%, Cr: at most 1.0%, Mo: at most0.8%, V: at most 0.2%, Nb: at most 0.06%, and Ti: at most 0.05%.